Cathodes (Lithium-ion batteries)
Lithium insertion materials are common as cathodes in rechargeable Li-ion batteries. Both structure and properties of these materials are crucial to the function of the complete battery. Our research covers a wide range of aspects on cathode materials:
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The energy available depends on how much lithium can be extracted reversibly. Polyanionic cathodes such as lithium iron silicate (Li2FeSiO4) is a promising cathode material with high capacity and low cost.
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Charge and discharge properties can be affected by particle size and morphology of the electrode materials. We synthesise and characterise a number of nano-structured cathode materials using different techniques.
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The lifetime of a battery depends on reactions between the electrodes and the electrolyte. We use Photoelectron Spectroscopy (PES) to study how side-reactions affect the cathode surface and interface.
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Theoretical calculations, especially DFT calculations, can help rationalise the structure, diffusion mechanisms, and dopant effects. This will also provide some atomic level understanding and functionality.
Funding
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VINNOVA
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Swedish Research Council (VR)
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Swedish Energy Agency (STEM)